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Role of fluorine doping on luminescence centers and enhanced photocatalytic performance of nebulizer sprayed TiO 2 films under visible light

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Abstract Visible light active fluorine modified TiO2 thin films were deposited through simple and low-cost nebulizer spray technique. The structural and morphological studies of the prepared films were investigated by… Click to show full abstract

Abstract Visible light active fluorine modified TiO2 thin films were deposited through simple and low-cost nebulizer spray technique. The structural and morphological studies of the prepared films were investigated by X-ray diffraction and scanning electron microscopy. The chemical state of the elements over the film surface was analyzed by X- ray photoelectron spectroscopy. The optical absorption studies revealed a noticeable reduction in the band gap due to the inclusion of F atom into TiO2 lattice. Photoluminescence spectra exhibited the enhancement of fluorine-induced oxygen vacancies and effective charge separation due to the formation of Ti3+ ions in F-TiO2 thin films. Doping of fluorine on TiO2 lattice showed an effective increase in photocatalytic degradation performance with good stability and repeatability under visible light.

Keywords: nebulizer; visible light; luminescence; performance; fluorine; role fluorine

Journal Title: Journal of Luminescence
Year Published: 2018

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