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NIR emitting Bi2MoO6:Nd3+/Yb3+ phosphor as a spectral converter for solar cells

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Abstract Bi2MoO6 had been studied as a photocatalyst, ferroelectric, anti-bacterial, microwave dielectric, etc. No significant studies on the luminescence in Bi2MoO6 had been previously reported. In this work, NIR emission… Click to show full abstract

Abstract Bi2MoO6 had been studied as a photocatalyst, ferroelectric, anti-bacterial, microwave dielectric, etc. No significant studies on the luminescence in Bi2MoO6 had been previously reported. In this work, NIR emission of Nd3+ activator sensitized by Bi2MoO6 host is reported. The excitation is in form of a broad band covering entire nUV-blue region of the spectrum. NIR emission around 1 µm and the broad band excitation is highly suitable for several applications like modification of solar spectrum for solar photovoltaics. Apart from Nd3+ emission, NIR emission around 979 nm resulting from Nd3+→ Yb3+ energy transfer is also reported. Mechanisms of host → Nd3+ and Nd3+→ Yb3+ energy transfer are suggested.

Keywords: bi2moo6; nir emitting; nd3 yb3; nir emission

Journal Title: Journal of Luminescence
Year Published: 2019

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