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Reverse photodegradation of infrared luminescence of colloidal Ag2S quantum dots

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Abstract Regularities of reverse photodegradation of infrared (IR) luminescence of colloidal Ag2S quantum dots (QDs), stabilized in gelatin with the average size of 1.6 nm ( λ lum max = 1205 nm) and… Click to show full abstract

Abstract Regularities of reverse photodegradation of infrared (IR) luminescence of colloidal Ag2S quantum dots (QDs), stabilized in gelatin with the average size of 1.6 nm ( λ lum max = 1205 nm) and passivated with thyoglicolic acid with the average size of 2.3 nm ( λ lum max = 1095 nm) were discussed. The photochemical nature of this process was found. The evidences of the formation of nonradiative recombination centers near the IR luminescence centers was found. These centers disintegrate in the dark with the activation energy of 0.9 eV and ensure the recovery of intensity IR luminescence of Ag2S QDs by 65–75%.

Keywords: infrared luminescence; colloidal ag2s; reverse photodegradation; luminescence; luminescence colloidal; photodegradation infrared

Journal Title: Journal of Luminescence
Year Published: 2019

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