Abstract Eu3+ and Ag nanoparticles (Ag-NPs) doped high silica glass (HSG) was synthesized by absorbing and sintering porous glass. The effect of localized surface plasmon resonance (LSPR) of Ag-NPs on… Click to show full abstract
Abstract Eu3+ and Ag nanoparticles (Ag-NPs) doped high silica glass (HSG) was synthesized by absorbing and sintering porous glass. The effect of localized surface plasmon resonance (LSPR) of Ag-NPs on absorbance, luminescence properties and decay curves was investigated. The results indicate that Ag-NPs are effectively doped into HSG. The surface plasmon coupling can be formed between the Eu3+ ions and the Ag-NPs surface because the broad absorption band of Ag-NPs overlaps with the excitation peaks of Eu3+. The profiles of the excitation and emission spectra were not affected by Ag-NPs. By optimizing the Ag concentration, the emission intensity and quantum yield (QY) of HSG-Eu3+-0.1%Ag are significantly higher than those of HSG-Eu3+. Plasmon-enhanced luminescence can occur through enhancement of local electromagnetic field and radiative decay rate.
               
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