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Engineering near-infrared emitting scintillators with efficient Eu2+ → Sm2+ energy transfer

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Abstract Recently, we proposed a concept for a new class of near infrared (NIR) scintillators by employing efficient Eu2+ → Sm2+ energy transfer. In this article we investigate the optical… Click to show full abstract

Abstract Recently, we proposed a concept for a new class of near infrared (NIR) scintillators by employing efficient Eu2+ → Sm2+ energy transfer. In this article we investigate the optical spectroscopy of Sm2+ in BaBrI, CsSrI3, and CsBa2I5 halide hosts. A criterion was derived for fast Sm2+ 5d → 4f emission and a list of new potential NIR scintillators is proposed.

Keywords: energy transfer; sm2; near infrared; sm2 energy; efficient eu2; eu2 sm2

Journal Title: Journal of Luminescence
Year Published: 2020

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