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The effect of copper on the structural and thermoluminescence properties of aluminium borate

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Abstract The thermoluminescence of aluminium borate doped to different concentrations of copper is reported. Samples of Al2(B4O7)3:Cu were prepared by high-temperature solid-state sintering. Scanning electron microscopy showed a difference in… Click to show full abstract

Abstract The thermoluminescence of aluminium borate doped to different concentrations of copper is reported. Samples of Al2(B4O7)3:Cu were prepared by high-temperature solid-state sintering. Scanning electron microscopy showed a difference in the grain size for the copper doped and undoped aluminium borate with particulates of the undoped sample in the size 60–80 nm whereas those of the undoped sample were in the range 40–50 nm. Studies using Fourier transform infrared spectroscopy showed that copper doping of aluminium borate reduces transmittance and results in more absorbance in the various spectral regions. Thermoluminescence from all samples measured at 1oCs−1 following irradiation to 150 Gy shows a prominent peak near 98 °C with a secondary, weaker-intensity peak at 168 °C.Both peaks are subject to non-first-order kinetics and the dose response is affected by doping.

Keywords: aluminium borate; effect copper; copper; thermoluminescence; copper structural

Journal Title: Journal of Luminescence
Year Published: 2020

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