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Abstract A series of double-stranded DNA samples, containing cholesteric liquid crystal droplets, were investigated. Binding of DNA molecules with Gd 3+ , La 3+ , Cu 2+ , ions was… Click to show full abstract
Abstract A series of double-stranded DNA samples, containing cholesteric liquid crystal droplets, were investigated. Binding of DNA molecules with Gd 3+ , La 3+ , Cu 2+ , ions was carried out. The samples were characterized by X-ray, optical circular dichroism and EPR techniques. Magnetic SQUID magnetometer research showed significant deviations of Gd 3+ paramagnetism from the Curie-Weiss law. A possibility of spin-glass-like interactions was analyzed. The dispersion of magnetic parameters was claimed as a main reason of magnetic anomalies observed in the liquid crystal DNA-metal systems. Such systems can be useful in biomedical applications as low-toxic magnetic labels.
Journal Title: Journal of Magnetism and Magnetic Materials
Year Published: 2017
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