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Interface elasticity effects in polymer-filled nanoporous metals

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A continuum formulation for electroactive composites made from nanoporous gold and ion-conducting polymer is proposed. A novel extension of surface elasticity theory is developed to account for the high surface-to-volume… Click to show full abstract

A continuum formulation for electroactive composites made from nanoporous gold and ion-conducting polymer is proposed. A novel extension of surface elasticity theory is developed to account for the high surface-to-volume ratio of nanoporous gold, and to capture the chemoelectromechanical coupling that occurs on the interface between the metal and the polymer. This continuum formulation accounts for the fully non-linear behaviour exhibited by the composite. The balance of linear momentum, Gaus's flux theorem and a relation for the transport of charge carriers are introduced in the bulk material as well as on the interface to describe the non-linear multiphysics and highly coupled response of the actuator. The resulting system of non-linear equations is solved using the finite element method. A series of numerical examples is presented to elucidate the theory.

Keywords: elasticity; effects polymer; interface elasticity; non linear; polymer filled; elasticity effects

Journal Title: Journal of The Mechanics and Physics of Solids
Year Published: 2017

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