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Compact, low-cost NMR spectrometer and probe for dissolution DNP.

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The desire for higher magnetic resonance sensitivity has led to the development of multiple home-built and commercial dissolution dynamic nuclear polarization polarizers. The emergence of polarizers capable of variable magnetic… Click to show full abstract

The desire for higher magnetic resonance sensitivity has led to the development of multiple home-built and commercial dissolution dynamic nuclear polarization polarizers. The emergence of polarizers capable of variable magnetic field strengths desires a versatile standalone spectrometer and NMR circuit to fulfill detection needs at different frequencies. We present a benchtop NMR spectrometer with a duplexer capable of serving high-field solid and liquid state NMR applications up to 450 MHz. A detailed view of the employed probe is discussed. Tuning and matching schemes are investigated yielding and experimentally verifying closed-form equations to estimate the nutation frequency for a remotely tuned and matched sample coil.

Keywords: nmr; nmr spectrometer; probe; compact low; spectrometer; dissolution

Journal Title: Journal of magnetic resonance
Year Published: 2019

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