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Comparative study of Cr, V and W recovery from a self-reduction briquette and a steel-briquette system

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Abstract The objective of this study was to analyze the recycling possibility of the electric arc furnace dust (EAFD) in the form of a briquette. This paper studied the kinect… Click to show full abstract

Abstract The objective of this study was to analyze the recycling possibility of the electric arc furnace dust (EAFD) in the form of a briquette. This paper studied the kinect behavior of the briquette's self-reduction and in contact with molten steel (steel-briquette system) and it was aimed at finding the optimal briquette composition used to recover elements such as Cr, V and W. Thermodynamic simulations with FactSage were carried out to validate the experimental results. The EAFD material as-received was magnetically separated to the form of a magnetic electric arc furnace dust (MEAFD) then characterized analytically and microstructurally. Analytical characterization demonstrated that the EAFD was rich in Cr, W and V. Microstructural analyses revealed the presence of oxides and spinel phases. Three different compositions of briquettes were prepared for the experiments: the first with 84% of MEAFD and 16% C; the second with 82% of MEAFD and 18% C; and the third with 80% of MEAFD and 20% C. Reduction experiments at the temperature of 1500 °C were carried out to study the reduction rate differences in the briquettes and the steel-briquettes systems. Reduction experiments showed that the fastest reaction occurred in the briquette with 20% C for both systems. Among the wide experimental dataset analyzed, the optimal measured recovery was 48.1% Cr, 72.7% W and 47.5% V (in wt%).

Keywords: reduction; self reduction; briquette; briquette system; steel briquette

Journal Title: Journal of materials research and technology
Year Published: 2020

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