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On the photoluminescence and energy transfer of SrGa12O19:Cr3+,Nd3+ microscale NIR phosphors

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Abstract This work concerns Cr3+ and Nd3+ co-activated SrGa12O19 phosphors, which were synthesized by high temperature solid-state method using oxides and carbonates as starting materials. Luminescent samples according to SrGa12O19:Cr3+,Nd3+… Click to show full abstract

Abstract This work concerns Cr3+ and Nd3+ co-activated SrGa12O19 phosphors, which were synthesized by high temperature solid-state method using oxides and carbonates as starting materials. Luminescent samples according to SrGa12O19:Cr3+,Nd3+ comprise Cr3+ for the absorption of UV and visible radiation (250–700 nm) prior to energy transfer to Nd3+. The result of the energy transfer between Cr3+ and Nd3+ is the observation of line emission originating from Nd3+ in the near infrared range. The energy transfer from Cr3+ to Nd3+ is discussed via the variations of the lifetime values of Cr3+, and the thermal quenching behavior is also described. The strong absorption of Cr3+ in the visible range and the efficient energy transfer from Cr3+ to Nd3+ indicate that the herein presented material type can serve as a radiation converter to improve the efficiency of photovoltaic devices based on silicon cells.

Keywords: cr3; cr3 nd3; srga12o19; energy transfer

Journal Title: Journal of materials research and technology
Year Published: 2021

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