Abstract To analyze the C8 light hydrocarbon of absorbed gas in the source rock and natural gas, both the PY-GC and GC were applied. This is done in order to… Click to show full abstract
Abstract To analyze the C8 light hydrocarbon of absorbed gas in the source rock and natural gas, both the PY-GC and GC were applied. This is done in order to develop the discrimination parameters of different genetic gases. Eight samples, including six mudstones with type II1 and type I organic matter and two coals, were analyzed by PY-GC. On the other hand, the sixteen typical coal-derived gases and sixteen oil-associated gases were analyzed by GC. The results show that there exists a great difference in the ratio of 2-methylheptane and 1-cis-3-dimethylcyclohexane in coal-derived gases, oil-associated gases, and source rock absorbed gases. The ratio in coal-derived gases is less than 0.5, whereas it is higher than 0.5 in oil-associated gases. In addition, there are also differences in the relative composition of C8 normal alkanes, isoparaffin, and cycloparaffin in coal-derived and oil-associated gases. Coal-derived gas is characterized by high cycloparaffin content that is generally higher than 40%, while the oil-associated gas exhibits low cycloparaffin content that generally less than 40%, as well as high isoparaffin content. Therefore, these parameters can be used to identify a coal-derived gas from an oil-associated gas.
               
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