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Effect of Ce addition on the glass-forming ability and hard-magnetic properties of the Nd-Fe-Al bulk metallic glasses

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Abstract The influence of Ce addition on the glass-forming ability (GFA) and hard-magnetic properties of the Nd 60 −  x Ce x Fe 30 Al 10 ( x  = 0 − 35) alloy… Click to show full abstract

Abstract The influence of Ce addition on the glass-forming ability (GFA) and hard-magnetic properties of the Nd 60 −  x Ce x Fe 30 Al 10 ( x  = 0 − 35) alloy prepared by suction casting have been investigated. The glass-forming ability of the as-cast rods increased with the addition of Ce content from x  = 0 to x  = 30, and then decreased for x  = 35. The as-cast rods with a composition of x  = 0 and x  = 30 contained two amorphous magnetic phases including Fe-rich regions and Nd-rich regions characterized by the Curie temperature T c1 and T c2 . The Ce atoms may be unevenly distributed in the two magnetic phases, which prefer to substitute Nd in the low T c phase. All the alloys exhibit hard magnetic behavior, while the room-temperature coercivity and remanence gradually decrease with the Ce addition. The saturation magnetization ( M s ), remanence ( M r ) and coercivity ( i H c ) of the alloy for x  = 30 with the best glass-forming ability are 16.30 Am 2 /kg, 10.22 Am 2 /kg and 162.31 kA/m, respectively.

Keywords: glass forming; hard magnetic; forming ability; addition

Journal Title: Journal of Non-crystalline Solids
Year Published: 2017

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