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Ultralow sintering temperature and permittivity with excellent thermal stability in novel borate glass-ceramics

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Abstract A novel CuO-ZnO-B2O3-Li2O glass-ceramic was prepared by solid phase method, and. Its phase transition, sintering and dielectric performance was studied. No crystalline phase is observed for the specimen sintered… Click to show full abstract

Abstract A novel CuO-ZnO-B2O3-Li2O glass-ceramic was prepared by solid phase method, and. Its phase transition, sintering and dielectric performance was studied. No crystalline phase is observed for the specimen sintered at 560 °C. However, the samples sintered at 580 °C and 600 °C, consist of ZnB4O7 and Cu2B4O7. And the Li2CuB4O8 appears with further increasing temperature. The er and τf change slightly but the Q × f value alter greatly with firing temperature. The glass-ceramic fired at 620 °C possesses optimum properties with er = 3.33, Q × f = 17,724 GHz and τf ≈ 0 ppm/°C. Furthermore, the as-prepared glass-ceramic exhibits good co-firing compatibility with Ag and Al electrode. These properties qualify the dielectric material as promising alternatives for wireless communication applications.

Keywords: temperature permittivity; sintering temperature; glass ceramic; temperature; ultralow sintering; glass

Journal Title: Journal of Non-Crystalline Solids
Year Published: 2019

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