Abstract Phosphate-based monazite ceramic is considered worldwide as a potential crystalline host matrix for immobilization of long-lived tri- and tetra-valent actinides present in high-level nuclear waste. Monazite is chemically stable… Click to show full abstract
Abstract Phosphate-based monazite ceramic is considered worldwide as a potential crystalline host matrix for immobilization of long-lived tri- and tetra-valent actinides present in high-level nuclear waste. Monazite is chemically stable with respect to the leaching processes and has high radiation stability. The present paper describes the influence of charged coupled (Ca 2+ , Th 4+ ) substitution in place of La 3+ on thermodynamic stability of synthetic monazite ceramics. XRD-analysis of Ca, Th substituted LaPO 4 viz., La 1-x Ca x/2 Th x/2 PO 4 (0 ≤ x ≤ 1) points to the formation of ideal solid-solution in the entire range of composition. However, thermodynamic analysis indicates deviation from ideal solid-solution with a minima at x = 0.25. The substituted La 1-x Ca x/2 Th x/2 PO 4 system is found to be iso-entropic and stabilized mainly by enthalpy. Enthalpies of formation as a function of Ca 2+ , Th 4+ substitution were analysed to provide insights into the development of thermodynamically stable nuclear waste matrix.
               
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