Photo by a2eorigins from unsplash
Abstract Secondary phosphine selenides react with acylacetylenes in water to form bis(2-acylvinyl) selenides. The reaction proceeds without catalyst and organic solvent under mild conditions (70–72 °C, 3 h), the corresponding divinyl selenides… Click to show full abstract
Abstract Secondary phosphine selenides react with acylacetylenes in water to form bis(2-acylvinyl) selenides. The reaction proceeds without catalyst and organic solvent under mild conditions (70–72 °C, 3 h), the corresponding divinyl selenides being isolated as a mixture of ( Z,Z )- and ( E,Z )-isomers in a yield of up to 78%.
Keywords:
phosphine selenides;
water;
acylvinyl selenides;
secondary phosphine;
bis acylvinyl
Journal Title: Journal of Organometallic Chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Journal of Organometallic Chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!