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Synthesis of ferrocene indanone derivatives via trinuclear N-heterocyclic carbene palladium(II)-catalyzed cyclocarbonylation of o-bromoarylferrocene

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Abstract A new route to ferrocene indanone derivatives has been developed via the trinuclear N-heterocyclic carbene palladium(II)-catalyzed carbonylative C-C bond formation. Under a CO atmosphere, using o-bromoarylferrocene as substrate, this… Click to show full abstract

Abstract A new route to ferrocene indanone derivatives has been developed via the trinuclear N-heterocyclic carbene palladium(II)-catalyzed carbonylative C-C bond formation. Under a CO atmosphere, using o-bromoarylferrocene as substrate, this reaction proceeded smoothly to give the desired products in moderate to excellent yields within hours.

Keywords: via trinuclear; trinuclear heterocyclic; carbene palladium; ferrocene indanone; indanone derivatives; heterocyclic carbene

Journal Title: Journal of Organometallic Chemistry
Year Published: 2018

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