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First molecular conductors of BPDT-TTF with metallacarborane anions: (BPDT-TTF)[3,3′-Сr(1,2-C2B9H11)2] and (BPDT-TTF)[3,3′-Сo(1,2-C2B9H11)2] – Synthesis, structure, properties

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Abstract The first molecular conductors based on bis(1,3-propylenedithio)tetrathiafulvalene and transition metal bis(dicarbollides) (BPDT-TTF)[3,3′-Сr(1,2-C2B9H11)2] (1) and (BPDT-TTF)[3,3′-Сo(1,2-C2B9H11)2] (2) were synthesized and their crystal structures were determined by X-ray analysis. The electric… Click to show full abstract

Abstract The first molecular conductors based on bis(1,3-propylenedithio)tetrathiafulvalene and transition metal bis(dicarbollides) (BPDT-TTF)[3,3′-Сr(1,2-C2B9H11)2] (1) and (BPDT-TTF)[3,3′-Сo(1,2-C2B9H11)2] (2) were synthesized and their crystal structures were determined by X-ray analysis. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature.

Keywords: c2b9h11 bpdt; molecular conductors; first molecular; ttf c2b9h11; bpdt ttf

Journal Title: Journal of Organometallic Chemistry
Year Published: 2018

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