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Abstract The direct S-cyclopropylation of thiophenols using tricyclopropylbismuth is reported. The reaction is catalyzed by copper(II) acetate and operates under mild conditions to afford the corresponding aryl cyclopropyl sulfides in… Click to show full abstract
Abstract The direct S-cyclopropylation of thiophenols using tricyclopropylbismuth is reported. The reaction is catalyzed by copper(II) acetate and operates under mild conditions to afford the corresponding aryl cyclopropyl sulfides in moderate to good yields. This reaction represents the first use of an organobismuth reagent in C(sp3)–S bond formation.
Keywords:
cyclopropyl sulfides;
thiophenols using;
using tricyclopropylbismuth;
first use;
cyclopropylation thiophenols;
aryl cyclopropyl
Journal Title: Journal of Organometallic Chemistry
Year Published: 2019
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Journal Title: Journal of Organometallic Chemistry
Year Published: 2019
Link to full text (if available)
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recommendations!