Abstract The reaction between aryl substituted α-olefins and dichloro(diisopropylamino)borane catalyzed with Cp 2 TiCl 2 leads to trans -1-alkenyl(chlorodiisopropylamino)boranes in high yields. Aliphatic α -olefins in this reaction give borylation… Click to show full abstract
Abstract The reaction between aryl substituted α-olefins and dichloro(diisopropylamino)borane catalyzed with Cp 2 TiCl 2 leads to trans -1-alkenyl(chlorodiisopropylamino)boranes in high yields. Aliphatic α -olefins in this reaction give borylation and hydroboration products, namely, trans -1-alkenyl(chlorodiisopropylamino)boranes and alkyl(chlorodiisopropylamino)-boranes. A proposed catalytic cycle for the Cp 2 TiCl 2 -catalyzed borylation of α -olefins with i -Pr 2 NBCl 2 is discussed.
Journal Title: Journal of Organometallic Chemistry
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!