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Abstract The preparation and structures of 6,6-diorganylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines containing the N→Si intramolecular dative bond are described. The complexes were characterized by NMR (1H, 13C, 29Si), IR and UV spectra. The crystal… Click to show full abstract
Abstract The preparation and structures of 6,6-diorganylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines containing the N→Si intramolecular dative bond are described. The complexes were characterized by NMR (1H, 13C, 29Si), IR and UV spectra. The crystal structures of 6-methyl-6-phenyl- and 6-(chloromethyl)-6-methylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines were determined by X-ray diffraction.
Keywords:
pentacoordinate silicon;
chemistry;
compounds based;
based dihydroxyazobenzene;
dihydroxyazobenzene ligand;
silicon compounds
Journal Title: Journal of Organometallic Chemistry
Year Published: 2019
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Journal Title: Journal of Organometallic Chemistry
Year Published: 2019
Link to full text (if available)
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recommendations!