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Supramolecular architecture of diammonium ferrocene-1,1′-diyldi(methylphosphinate)

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Abstract The ammonium salt of 1,1′-ferrocenylene-bis(methylphosphinic) acid was obtained and structurally characterized. The salt forms a supramolecular 3D structure due to hydrogen bonds between the layers formed by ammonium cations… Click to show full abstract

Abstract The ammonium salt of 1,1′-ferrocenylene-bis(methylphosphinic) acid was obtained and structurally characterized. The salt forms a supramolecular 3D structure due to hydrogen bonds between the layers formed by ammonium cations and 1,1′-ferrocenylene-bis(methylphosphinic) acid dianions. It is found that the methyl substituent in the salt does not prevent the formation of hydrogen bonds in three-dimensional space.

Keywords: architecture diammonium; supramolecular architecture; diyldi methylphosphinate; salt; ferrocene diyldi; diammonium ferrocene

Journal Title: Journal of Organometallic Chemistry
Year Published: 2019

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