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Abstract The photophysical properties of heteroleptic cyclometalated NHC iridium(III) complexes with bulky acetylacetonates have previously not been explored. To fill this gap, we prepared a new heteroleptic iridium(III) complex and… Click to show full abstract
Abstract The photophysical properties of heteroleptic cyclometalated NHC iridium(III) complexes with bulky acetylacetonates have previously not been explored. To fill this gap, we prepared a new heteroleptic iridium(III) complex and measured its photophysical properties. We investigated the electronic properties by means of DFT calculations (PBE0/6-311G∗) and propose a possible mechanism for the radiationless deactivation from the excited state.
Keywords:
iridium iii;
cyclometalated nhc;
iridium;
nhc iridium;
heteroleptic cyclometalated
Journal Title: Journal of Organometallic Chemistry
Year Published: 2020
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Journal Title: Journal of Organometallic Chemistry
Year Published: 2020
Link to full text (if available)
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recommendations!