Abstract Picolyl and benzyl linked biphenyl nickel NHC complexes [NiL1Br2] (1), [NiL2]Br2 (2) [NiL3]Br2 (3) and [NiL3(N3)2] (4) were synthesized and characterized by CHN, ESI-MS, 1H, 13C NMR and single… Click to show full abstract
Abstract Picolyl and benzyl linked biphenyl nickel NHC complexes [NiL1Br2] (1), [NiL2]Br2 (2) [NiL3]Br2 (3) and [NiL3(N3)2] (4) were synthesized and characterized by CHN, ESI-MS, 1H, 13C NMR and single crystal XRD. All complexes adopted distorted square planar structure. They were employed as catalysts in Suzuki-Miyaura cross-coupling reaction to afford different biphenyls in good to moderate yields.
Keywords:
biphenyl nickel;
benzyl linked;
nhc complexes;
nickel nhc;
picolyl benzyl;
linked biphenyl
Journal Title: Journal of Organometallic Chemistry
Year Published: 2021
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Journal Title: Journal of Organometallic Chemistry
Year Published: 2021
Link to full text (if available)
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recommendations!