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Zn-Sn Interdigitated Eutectic Alloy Anodes with High Volumetric Capacity for Lithium-Ion Batteries

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Summary Zn-Sn interdigitated eutectic alloy (IdEA) foils are highly promising anodes for lithium-ion batteries. Synthesized via severe plastic deformation, a two-phase alloy is converted into a nanostructured foil composed of… Click to show full abstract

Summary Zn-Sn interdigitated eutectic alloy (IdEA) foils are highly promising anodes for lithium-ion batteries. Synthesized via severe plastic deformation, a two-phase alloy is converted into a nanostructured foil composed of tin domains distributed throughout an electrically conductive zinc matrix. In addition to providing mechanical integrity, uncycled capacity in the zinc matrix eliminates the lithium-plating risk. These monolithic foil anodes offer an electrode-level volumetric capacity approximately double that of graphite (797 mA h cm−3), with a highly promising formation loss of

Keywords: interdigitated eutectic; alloy; capacity; eutectic alloy; lithium ion; ion batteries

Journal Title: Joule
Year Published: 2019

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