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Electrochemical performance of plate-like zinc cobaltite electrode material for supercapacitor applications

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Abstract The electrochemical performance of zinc cobaltite–based nanomaterial depends on its shape and morphology. Here we report on the electrochemical performance of plate-like zinc cobaltite nanocrystalline material synthesized via a… Click to show full abstract

Abstract The electrochemical performance of zinc cobaltite–based nanomaterial depends on its shape and morphology. Here we report on the electrochemical performance of plate-like zinc cobaltite nanocrystalline material synthesized via a facile hydrothermal method. The synthesized material was characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and Brunauer-Emmett-Teller analysis. It was found to be a single-phase zinc cobaltite nanocrystalline material with a cubic spinel crystal structure. The electrochemical performance of the synthesized plate-like zinc cobaltite nanocrystalline material was evaluated by cyclic voltammetry, cyclic chronopotentiometry and electrochemical impedance spectroscopy. The plate-like zinc cobaltite nanocrystalline material displayed a maximum coulombic efficiency of 78% and a maximum specific capacitance of 812 F/g, and it retained 88% of its capacitance after 5100 cycles. Such electrochemical performance may qualify the plate-like zinc cobaltite nanocrystalline material as a potential electroactive material in supercapacitors.

Keywords: zinc cobaltite; material; spectroscopy; plate like; electrochemical performance

Journal Title: Journal of Physics and Chemistry of Solids
Year Published: 2018

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