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Effective energy harvesting in thin film organic solar cells using Ni:Zn as bimetallic nanoparticles

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Abstract This article explores the effect of bimetallic plasmonic nanocomposites in the solar absorber layers of thin-film organic solar cells (TFOSCs) for possible improvement in harvesting solar energy. To achieve… Click to show full abstract

Abstract This article explores the effect of bimetallic plasmonic nanocomposites in the solar absorber layers of thin-film organic solar cells (TFOSCs) for possible improvement in harvesting solar energy. To achieve this goal, a new nanocomposite composed of Nickel and Zinc (Ni: Zn) was successfully synthesized by the use of a chemical reduction processes. The effect of bimetallic nanocomposites was studied using a photoactive medium, which comprises of poly-(3-hexylthiophene) (P3HT) [6,6]-phenyl C61 butyric acid methyl ester (PC61BM) blend and doped with Ni:Zn at different concentrations. Consequently, an improved power conversion efficiency value up to 4.78% was found at 1% Ni:Zn bimetallic concentration by weight compared to reference solar cell. This is a clear indication of the influence of Ni:Zn bimetallic nanoparticles on the performance of TFOSC. These effects have been realized by the occurrence of local surface plasmon resonance (LSPR) phenomenon caused by Ni: Zn nanoparticles in polymer medium.

Keywords: organic solar; solar; bimetallic nanoparticles; thin film; film organic; solar cells

Journal Title: Journal of Physics and Chemistry of Solids
Year Published: 2022

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