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Facile synthesis of rGO@In2S3@UiO-66 ternary composite with enhanced visible-light photodegradation activity for methyl orange

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Abstract In this study, rGO@In2S3@UiO-66 ternary composites have been designed and fabricated via a facile two-step hydrothermal process and used as visible-light-driven photocatalyst. The as-prepared samples have been characterized by… Click to show full abstract

Abstract In this study, rGO@In2S3@UiO-66 ternary composites have been designed and fabricated via a facile two-step hydrothermal process and used as visible-light-driven photocatalyst. The as-prepared samples have been characterized by PXRD, SEM, TEM, XPS, UV–vis DRS, PC, PL and BET. The photocatalytic performance is evaluated by the degradation of methyl orange (MO) under visible-light irradiation. The results show that the photocatalytic performance of rGO@In2S3@UiO-66 is superior to that of In2S3, UiO-66 and In2S3@UiO-66. The enhanced photocatalytic performance of rGO@In2S3@UiO-66 can be attributed to the relative large specific surface area, the improving light absorption region caused by rGO and the promoting the separation of photo-induced carriers by the synergistic effect of rGO, In2S3 and UiO-66. In addition, the rGO@In2S3@UiO-66 composites also demonstrate outstanding photocatalytic stability and there is only 5.8% loss of degradation rate after five cycles. Furthermore, the reasonable photocatalytic mechanism for the degradation of MO by rGO@In2S3@UiO-66 was also proposed.

Keywords: in2s3; visible light; in2s3 uio; uio ternary; rgo in2s3

Journal Title: Journal of Photochemistry and Photobiology A: Chemistry
Year Published: 2019

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