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Engineering Titanium-Organic Framework Decorated Silver Molybdate and Silver Vanadate as Antimicrobial, Anti-cancer Agents, and Photo-induced Hydroxylation Reactions

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Abstract Hydroxylation is a chemical process that presents a hydroxyl group (-OH) into a natural compound. It is greatly vital in detoxification of unsafe compounds to clean the environment and… Click to show full abstract

Abstract Hydroxylation is a chemical process that presents a hydroxyl group (-OH) into a natural compound. It is greatly vital in detoxification of unsafe compounds to clean the environment and giving new functionality to organic compounds. Therefore, investigation multi-properties of metal organic frameworks (MOFs) are most critical field. Here, titanium based MOFs (MIL-125-NH2) was enhanced with silver molybdate (Ag2MoO4) and silver vanadate (AgVO3) nanocrystals. The component of joining Ag2MoO4 and AgVO3 into MIL-125-NH2 network has been examined. The novel arranged composites were tried to change aromatic-Cl into aromatic-OH, the chemical response continues through the addition–elimination reactions. The expansion of our work focuses on examining the effect of MOFs on both of antimicrobial and anticancer agents. Surprising data comes over when using Ag2MoO4@MIL-125-NH2 nanocomposite as anti-bacterial material; the inhibition zone was minimized (seven times less) when treated with a parent Ti-MOFs (MIL-125-NH2) match with its Ti-MOFs composite (Ag2MoO4@MIL-125-NH2). As well as, the potential of anti-cancer activity for Ti-MOFs composite (Ag2MoO4@MIL-125-NH2) display 1.58 times more than a parent Ti-MOFs.

Keywords: mil 125; 125 nh2; hydroxylation; silver molybdate; silver vanadate; anti cancer

Journal Title: Journal of Photochemistry and Photobiology A: Chemistry
Year Published: 2021

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