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CoNi alloy incorporated, N doped porous carbon as efficient counter electrode for dye-sensitized solar cell

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Abstract The design of efficient non-Pt counter electrode (CE) materials is highly desired in field of dye sensitized solar cell (DSC). Herein, by combining the catalytic features of N doped… Click to show full abstract

Abstract The design of efficient non-Pt counter electrode (CE) materials is highly desired in field of dye sensitized solar cell (DSC). Herein, by combining the catalytic features of N doped carbon (NC) and CoNi alloy, CoNi alloy incorporated porous N doped carbon hybrid (CoNi-NC) is synthesized for application as catalytic CE of DSC. Benefiting from the proper meso-/macroporosity with high electroactive surface area, the CoNi-NC electrode demonstrates apparently higher electrocatalytic activity for iodine reduction reaction (IRR) over pyrolyzed Pt electrode. As a consequence, the DSC based on CoNi-NC CE yields a power conversion efficiency ( PCE ) of 7.6%, which is superior over that of Pt CE based cell (7.2%), highlighting the bright potential of CoNi-NC in efficient and economical CE of DSC.

Keywords: carbon; coni alloy; counter electrode; electrode; cell

Journal Title: Journal of Power Sources
Year Published: 2017

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