Abstract A CoCe/ZSM-5 catalyst was prepared by ultrasonic-assisted impregnation for the catalytic combustion of toluene. To study the effect of Na+, a series of different Si/Al ZSM-5 zeolites and catalysts… Click to show full abstract
Abstract A CoCe/ZSM-5 catalyst was prepared by ultrasonic-assisted impregnation for the catalytic combustion of toluene. To study the effect of Na+, a series of different Si/Al ZSM-5 zeolites and catalysts doped with Na were synthesized. The experimental results show that 0.71 wt% of Na+ can inhibit active growth, generate more active small crystal grains, and promote improvement of the catalytic activity by the grain boundary segregation block mechanism, the catalyst with 90 vol% conversion of toluene at 250 °C. Over 0.71 wt% of Na+ content will neutralize the acid centre of the catalyst, lowering the specific surface area of the catalyst and resulting in a gradual decrease in the catalytic activity.
               
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