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Calcination temperature dependent structural modifications, tailored morphology and luminescence properties of MoO3 nanostructures prepared by sonochemical method

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Abstract MoO3 nanoparticles were prepared by a surfactant assisted sonochemical method. Final products were calcined at 180 °C, 400 °C, and 600 °C resulting in the ∝-orthorhombic, β-monoclinic, and h-hexagonal structures of MoO3,… Click to show full abstract

Abstract MoO3 nanoparticles were prepared by a surfactant assisted sonochemical method. Final products were calcined at 180 °C, 400 °C, and 600 °C resulting in the ∝-orthorhombic, β-monoclinic, and h-hexagonal structures of MoO3, respectively. Variable morphologies were also seen from SEM images. The energy band gap of the samples was estimated to be ∼3.60 eV from diffuse reflectance spectra using Kubelka- Munk function. Photoluminescence spectra exhibited a strong emission peak at ∼438 nm due to the hexa-coordinated [MoO6]5+dz2–dyz transitions. The results show that the samples can be used as blue light emitting components of white light emitting diodes.

Keywords: structural modifications; method; temperature dependent; calcination temperature; dependent structural; sonochemical method

Journal Title: Journal of Science: Advanced Materials and Devices
Year Published: 2017

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