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Porphyrinic zirconium-based MOF with exposed pyrrole Lewis base site as an efficient fluorescence sensing for Hg2+ ions, DMF small molecule, and adsorption of Hg2+ ions from water solution

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Abstract The microporous zirconium-based MOF, as known [PCN-221], was successfully prepared by the solvothermal reaction method using meso-tetra(4-carboxyphenyl) porphyrin (TCPP) as a ligand and used as a fluorescent sensor for… Click to show full abstract

Abstract The microporous zirconium-based MOF, as known [PCN-221], was successfully prepared by the solvothermal reaction method using meso-tetra(4-carboxyphenyl) porphyrin (TCPP) as a ligand and used as a fluorescent sensor for sensitive and selective recognition of Hg2+ ions, DMF small molecule, and adsorption of Hg2+ ions. The sensing of [PCN-221] showed a quenching response of Hg2+ ions with a fast fluorescent response rate under

Keywords: zirconium based; ions dmf; hg2; dmf small; hg2 ions; based mof

Journal Title: Journal of Solid State Chemistry
Year Published: 2020

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