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Novel multicolor-tunable phosphor Ba3B6Si2O16: Tb3+, Eu3+ - Luminescent properties and energy transfer for near-UV white LEDs

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Abstract Multicolor-tunable phosphors Ba3B6Si2O16: Tb3+, Eu3+ were synthesized by the high-temperature solid state method. Phase structure, luminescent properties and energy transfer were researched. All the doped ions have effectively replaced… Click to show full abstract

Abstract Multicolor-tunable phosphors Ba3B6Si2O16: Tb3+, Eu3+ were synthesized by the high-temperature solid state method. Phase structure, luminescent properties and energy transfer were researched. All the doped ions have effectively replaced part of Ba2+ sites in the host Ba3B6Si2O16. Under 377 ​nm excitation, the characteristic 4f-4f transitions of Tb3+ and Eu3+ ion are observed simultaneously and the luminescent color can be effectively tuned from green via yellow to red with the increase of Eu3+ concentration. Energy transfer from Tb3+ to Eu3+ was confirmed by photoluminescence spectra and luminescent decay curves. Ba3B6Si2O16: Tb3+, Eu3+ phosphors can be potentially useful in the application of NUV chip excited LEDs with wide band gap and good thermal stability.

Keywords: energy transfer; ba3b6si2o16 tb3; luminescent; tb3 eu3

Journal Title: Journal of Solid State Chemistry
Year Published: 2020

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