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N-doped mesocarbon microbeads-carbon nanotubes as high performance counter electrodes of a dye-sensitized solar cell

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Abstract N-doped mesocarbon microbeads-carbonnanotubes (N-MCMB-CNT) hybridare designed and directly explored as counter electrodes (CEs) for dye-sensitized solar cells (DSCs). In this hybrid, the CNTs are anchored onto the graphene-like nanoplatelets… Click to show full abstract

Abstract N-doped mesocarbon microbeads-carbonnanotubes (N-MCMB-CNT) hybridare designed and directly explored as counter electrodes (CEs) for dye-sensitized solar cells (DSCs). In this hybrid, the CNTs are anchored onto the graphene-like nanoplatelets of N-MCMB-CNT, and weave closely with each other to form a continuous network. This CNTs network bridges the gap between graphene-like nanoplatelets and acts as a wire for electron transfer between N-MCMB and CNTs. Furthermore, a high amount of pyridinic N and graphitic N atoms is doped to enhance the reactivity and electrocatalytic performance of N-MCMB-CNT. Integrating superior conductivity and electrocatalytic activity, the device with N-MCMB-CNT CE yield overall conversion efficiency of 6.08%, which is compared to that of the device with Pt CE (6.37%).

Keywords: mesocarbon microbeads; counter electrodes; dye sensitized; sensitized solar; doped mesocarbon; mcmb cnt

Journal Title: Journal of the Taiwan Institute of Chemical Engineers
Year Published: 2018

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