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Effect of benzyl substitution at different sites on the inhibition performance of pyrimidine derivatives for mild steel in highly acidic solution

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Abstract Three pyrimidine derivatives, 6-amino-2-(benzylthio)-4(3H)-pyrimidinone (BTP-1), 6-amino-3-benzyl-2-(benzylthio)-4(3H)-pyrimidinone (BTP-2) and 6-(benzyloxy)-2-(benzylthio)-4-pyrimidinamine (BTP-3), were synthesized as corrosion inhibitors for mild steel in 3 M HCl solution. The inhibition performance of these three pyrimidine… Click to show full abstract

Abstract Three pyrimidine derivatives, 6-amino-2-(benzylthio)-4(3H)-pyrimidinone (BTP-1), 6-amino-3-benzyl-2-(benzylthio)-4(3H)-pyrimidinone (BTP-2) and 6-(benzyloxy)-2-(benzylthio)-4-pyrimidinamine (BTP-3), were synthesized as corrosion inhibitors for mild steel in 3 M HCl solution. The inhibition performance of these three pyrimidine derivatives was studied by weight loss and electrochemical measurements, surface characterization, and theoretical calculations. It is found that these three pyrimidine derivatives act as mixed-type inhibitors with predominant cathodic effectiveness, and exhibit good inhibition performance with the order of BTP-1

Keywords: pyrimidine; mild steel; inhibition performance; pyrimidine derivatives

Journal Title: Journal of the Taiwan Institute of Chemical Engineers
Year Published: 2019

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