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A novel nitrogen-containing covalent organic framework adsorbent for the efficient removal of bisphenol A from aqueous solution

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Abstract Extensively used bisphenol A (BPA) in industry aggravates the pollution of water environment. Thus, we are committed to developing an efficient adsorbent to remove BPA, exploring the adsorption performance… Click to show full abstract

Abstract Extensively used bisphenol A (BPA) in industry aggravates the pollution of water environment. Thus, we are committed to developing an efficient adsorbent to remove BPA, exploring the adsorption performance and mechanism. Here, a novel nitrogen-containing covalent organic framework, named PyTTA-Dva-COF as an effective adsorbent for removing BPA from aqueous solutions was prepared by a simple solvent-thermal method. PyTTA-Dva-COF exhibited uniform nanofibrous structure, abundant and robust C=N functional groups, as well as high chemical stability. The saturated adsorption capacity is 285 mg/g, and the adsorption process conforms to Langmuir isotherm model. The kinetic data conforms to the pseudo-second-order kinetic model, and the thermodynamic parameters, ∆G°

Keywords: novel nitrogen; adsorbent; nitrogen containing; containing covalent; covalent organic; organic framework

Journal Title: Journal of The Taiwan Institute of Chemical Engineers
Year Published: 2020

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