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Highly improving the mechanical-responses/thermal-stability of the epoxy nano-composite using novel highly-oxidized multi-walled carbon nanotubes (OMWCNT) functionalized by Zinc-doped Polyaniline (PANI) nanofibers

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Abstract Herein, the synthesis of a novel highly-oxidized carbon nanotubes (OMWCNT) modified by the Emeraldine salt (ES)-based polyaniline (PANI) nanofibers (NFs) was carried out. The zinc doped OMWCNT-PANI particles were… Click to show full abstract

Abstract Herein, the synthesis of a novel highly-oxidized carbon nanotubes (OMWCNT) modified by the Emeraldine salt (ES)-based polyaniline (PANI) nanofibers (NFs) was carried out. The zinc doped OMWCNT-PANI particles were synthesized to achieve novel nanoparticles, enhancing the thermal/mechanical hallmarks and features of the epoxy nano-composite coatings. Various characterization methods were utilized to affirm the triumphant deposition of the Zn-linked PANI nanofibers on the OMWCNT network. The DMTA, TGA, and Raman examinations were applied to delineate the prepared nano-composite films' thermal/mechanical characteristics. The results disclosed that the inclusion of 0.15 wt% of OMWCNT-PANI-Zn into the epoxy matrix has a substantial efficacy on the thermomechanical properties. That is to say, the Tg, storage modulus, cross-linking density, and tensile strength increased about 10.5°C, 17%, 205%, and 137%, respectively, compared with the Neat/EP coating. Additionally, the remaining weight of 14% for OMWCNT-PANI-Zn/EP at 600°C evidenced the significant epoxy composite thermal stability enhancement.

Keywords: pani; pani nanofibers; carbon nanotubes; nano composite; novel highly; highly oxidized

Journal Title: Journal of The Taiwan Institute of Chemical Engineers
Year Published: 2021

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