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Uses of fluorescence excitation-emissions indices in predicting water treatment efficiency

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Membrane filtration is a possible alternative for the increase of the natural organic matter (NOM) content in the raw water sources in boreal areas. In a pilot study, a new… Click to show full abstract

Membrane filtration is a possible alternative for the increase of the natural organic matter (NOM) content in the raw water sources in boreal areas. In a pilot study, a new hollow fiber nanofilter (HFNF) has been tested. Water from four raw water sources were treated in membrane pilot plants, and three full-scale conventional plants were sampled. Three established fluorescence indices, humification index (HIX), fluorescence index (FI) and freshness index (β:α), were used for characterization, and were related to NOM removal by the two treatment methods Although the NOM removal in the treatment processes were related to SUVA, HIX has only a weak correlation to the total organic carbon (TOC) reduction of the HFNF, and none for the conventional treatment. FI and β:α are both correlated to the TOC reduction of the HFNF. Water hardness has a logarithmical correlation to the TOC reduction by the HFNF, plausibly due to moderation of the membrane surface. FI and β:α have potential to predict the efficiency of the HFNF and conventional treatment processes, and could be used online to identify changes in the raw water which affects the process efficiency.

Keywords: raw water; fluorescence; water; treatment; hfnf; efficiency

Journal Title: Journal of water process engineering
Year Published: 2017

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