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Reduction of thermal conductivity in Al2O3 dispersed p-type bismuth antimony telluride composites

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Abstract In this work, BiSbTe/Al2O3 composites were prepared by incorporation of alumina (with 2, 4, and 6 wt%) particles into the p-type Bi–Sb–Te gas atomized powders via mechanical milling and, subsequently… Click to show full abstract

Abstract In this work, BiSbTe/Al2O3 composites were prepared by incorporation of alumina (with 2, 4, and 6 wt%) particles into the p-type Bi–Sb–Te gas atomized powders via mechanical milling and, subsequently consolidated by spark plasma sintering (SPS). The Seebeck coefficient was significantly improved (over 41%) at 325 K, while the electrical conductivity was abruptly decreased for 6 wt% Al2O3 added BiSbTe/Al2O3 composites, which was mainly due to the decreases in carrier concentration, and energy filtering of carriers at interfaces. The thermal conductivity was eminently decreased over 27.5% for 6 wt% Al2O3 added BiSbTe/Al2O3 composites, was mainly attributed to the scattering of carriers and phonons at enormous grain boundaries as well as newly formed interfaces. The Vickers hardness of the BiSbTe/Al2O3 composites was improved compared to that of base matrix, and this was attributed to refinement of grains, and to a dispersion strengthening mechanism.

Keywords: al2o3 composites; bisbte al2o3; al2o3; thermal conductivity; conductivity; reduction thermal

Journal Title: Materials Chemistry and Physics
Year Published: 2019

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