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Surface engineering of layered SnO micro-plates for impressive high supercapacitor performance

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Abstract Tin monoxide is an important functional material, which is widely used in energy storage and optoelectronic devices. In this work, SnO micro-plates were synthesized by low-temperature hydrothermal method using… Click to show full abstract

Abstract Tin monoxide is an important functional material, which is widely used in energy storage and optoelectronic devices. In this work, SnO micro-plates were synthesized by low-temperature hydrothermal method using aqueous ammonia as reducing agent. The thickness and surface morphology of the SnO micro-plates were delicately controlled by adjusting ammonia concentration. It is shown that surface modification has significant effect on their supercapacitor performance. Specifically, an ultra-high specific capacity of 1080 F•g−1 is obtained, which reaches ~75% of its theoretical faradaic capacitance value. Considering the typical thickness of ~250 nm, the electrons/ions can diffuse ~90 nm into the sample. In addition, the capacity remains an impressive value of 849 F•g−1 after 1000 cycles at current density of 1 A•g−1, suggesting excellent stability. Our studies show that the non-transition metal oxide, SnO, is a promising supercapacitor electrode material with high specific capacity and good cycle stability.

Keywords: sno micro; supercapacitor performance; micro plates

Journal Title: Materials Chemistry and Physics
Year Published: 2019

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