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Room temperature magnetoelectric properties of [Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3]/Ni0.8Zn0.2Fe2O4 bilayer thin films deposited by laser ablation

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Abstract Ferroelectric-ferromagnetic [Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3](160 nm)/Ni0.8Zn0.2Fe2O4 (30 nm, 60 nm) bilayer thin films (abbreviated as (BZT-0.5BCT)/NZFO) have been grown on Pt/Si(100) substrate by pulse laser deposition techniques. X-ray diffraction analysis confirms polycrystalline nature of the… Click to show full abstract

Abstract Ferroelectric-ferromagnetic [Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3](160 nm)/Ni0.8Zn0.2Fe2O4 (30 nm, 60 nm) bilayer thin films (abbreviated as (BZT-0.5BCT)/NZFO) have been grown on Pt/Si(100) substrate by pulse laser deposition techniques. X-ray diffraction analysis confirms polycrystalline nature of the films without any intermediate phase at the interface. The large value of dielectric constant (e΄ ~ 2.03 × 103 at frequency 100 Hz) and remnant magnetization (Mr ~ 45.25 emu/cc) were observed at room temperature for (BZT-0.5BCT)/NZFO (60 nm) bilayer thin film. Bilayer (BZT-0.5BCT)/NZFO (30 nm) thin film exhibits saturated ferroelectric loop with large value of polarizations Pr ~ 5.57 μC/cm2 and Ps ~ 20 μC/cm2. The large value of ME coefficient (αE ~ 320 mV/cm.Oe) was obtained for (BZT-0.5BCT)/NZFO (30 nm) thin film at room temperature. This indicates its potential for lead-free ME device applications.

Keywords: zr0 2ti0; room temperature; bilayer thin; bilayer

Journal Title: Materials Chemistry and Physics
Year Published: 2020

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