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Enhancement of magnetocaloric properties in (1 − x)La0.7Ca0.2Sr0.1MnO3/xLa0.7Ca0.15Sr0.15MnO3 composite system (0 ≤ x ≤ 1)

Abstract The present work reveals an especial agreement between the experimental results and the continuous curves investigated by the numerical calculations in (1 − x)La0.7Ca0.2Sr0.1MnO3/xLa0.7Ca0.15Sr0.15MnO3 composite system. Moreover, the ability to adjust… Click to show full abstract

Abstract The present work reveals an especial agreement between the experimental results and the continuous curves investigated by the numerical calculations in (1 − x)La0.7Ca0.2Sr0.1MnO3/xLa0.7Ca0.15Sr0.15MnO3 composite system. Moreover, the ability to adjust the magnetic entropy change in a large temperature range is revealed to be possible by the mixture of both individual phases La0.7Ca0.2Sr0.1MnO3 and La0.7Ca0.15Sr0.15MnO3. Our samples have been synthesised using the solid state method. Rietveld refinements of the X-ray diffraction patterns show that both samples are single phase. The Curie temperature TC is found to be 308 K and 338 K for La0.7Ca0.2Sr0.1MnO3 and La0.7Ca0.15Sr0.15MnO3, respectively. Moreover, the magnetic entropy change and the Relative Cooling Power (RCP) values were estimated. We have shown that the optimum magnetocaloric effect at μ0H = 2T has been found for the composition with x = 0.45, which exhibits a table-like ΔS curve with a peak value slightly lowered and strongly expanded when comparing with the parent compounds.

Keywords: 15sr0 15mno3; 7ca0 15sr0; la0 7ca0; 1mno3 xla0; 7ca0 2sr0; 2sr0 1mno3

Journal Title: Materials Research Bulletin
Year Published: 2017

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