Abstract In this study, g-C 3 N 4 nanosheets coated UiO-66 nanohybrids were fabricated via a simple solvothermal method. The physicochemical parameters, structural and electrochemical properties of g-C 3 N… Click to show full abstract
Abstract In this study, g-C 3 N 4 nanosheets coated UiO-66 nanohybrids were fabricated via a simple solvothermal method. The physicochemical parameters, structural and electrochemical properties of g-C 3 N 4 /UiO-66 nanohybrids (CNUO-x) were investigated. The nanohybrids were systematically characterized by XRD, FT-IR, TGA, TEM, SEM, EDS elemental mappings, XPS, N 2 adsorption-desorption isotherms, PL and DRS. It was found that the addition of moderate g-C 3 N 4 could enhance the separation and migration rate of photo-induced charges, consequently leading to the increase of photocatalytic efficiency. The CNUO-1 nanohybrid exhibited better photocatalytic activity for the oxidation of Rh B under visible light irradiation, and displayed about 6.0 and 3.3 times faster than that of g-C 3 N 4 and UiO-66, respectively. Meanwhile, the nanohybrid showed excellent stability and reusability in four cyclic experiments. Finally, the increased photocatalytic reaction mechanism was also proposed. O 2 − , h + and OH were further found to be the main active contributors.
               
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