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Investigation on zinc substituted highly porous improved catalytic activity of NiFe2O4 nanocrystal by co-precipitation method

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Abstract Connecting to various applications of nickel ferrite as a ceramic magnetic nanocomposite in diverse manufacturing and technical categories, it is essential to optimize its optical, magnetic and microstructural characteristics.… Click to show full abstract

Abstract Connecting to various applications of nickel ferrite as a ceramic magnetic nanocomposite in diverse manufacturing and technical categories, it is essential to optimize its optical, magnetic and microstructural characteristics. Hence a facile route was developed to fabricate nickel zinc ferrite (Ni 1-x Zn x Fe 2 O 4 ) nanocomposites by co-precipitation route. The enviable spinel phase was studied by X-ray diffractometer and the crystallite size was found to vary from 8 to 15 nm. By Transmission Electron Microscopy, the micro structural and speck distribution was found in the range of 5–12.5 nm. Surface characterization was done using the isothermal BET technique which presents a high surface area that is exhibited by synthesized nanoparticles. Using Kubelka-Munk plot, bandgap was found to be decreasing with the increase of Zn concentration.The synthesized Ni 1-x Zn x Fe 2 O 4 was studied for its application in photo-Fenton degradation of organic Methylene blue (MB) dye. The synthesized nanocatalyst can bereused further which makes itself a proficient candidate in industrial effluent degradation.

Keywords: improved catalytic; porous improved; substituted highly; investigation zinc; highly porous; zinc substituted

Journal Title: Materials Research Bulletin
Year Published: 2018

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