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Near-infrared and blue cooperative Yb3+ luminescence in Lu3Sc2Ga3O12 nano-garnets

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Abstract Nanocrystalline Lu 3 Sc 2 Ga 3 O 12 garnet powders doped with different concentrations of trivalent ytterbium (Yb 3+ ) ions have been prepared by sol-gel method. These… Click to show full abstract

Abstract Nanocrystalline Lu 3 Sc 2 Ga 3 O 12 garnet powders doped with different concentrations of trivalent ytterbium (Yb 3+ ) ions have been prepared by sol-gel method. These garnet nano-powders have been characterized for their structural and luminescence properties using X-ray diffraction, diffuse reflectance and luminescence spectra. Near-infrared and blue cooperative upconversion luminescence spectra and decay curves of Yb 3+ ions in these nano-garnets have been measured as a function of the optically active ion concentration. Quenching of near-infrared and cooperative luminescence intensity beyond 5.0 mol% of Yb 3+ ion concentration have been observed. Variation of blue cooperative luminescence intensity with pump power has also been discussed.

Keywords: near infrared; nano garnets; blue cooperative; cooperative yb3; luminescence; infrared blue

Journal Title: Materials Research Bulletin
Year Published: 2018

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