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Enhancing the efficiency of quasi-solid-state dye-sensitized solar cells by adding bis(trifluoromethane)sulfonimide lithium salt and camphorsulfonic acid to gel-based electrolytes

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Abstract In this study, gel-based electrolytes were produced by mixing a liquid-based electrolyte with poly(methyl methacrylate) (PMMA), which served as a gelator to enhance the stability of the electrolytes and… Click to show full abstract

Abstract In this study, gel-based electrolytes were produced by mixing a liquid-based electrolyte with poly(methyl methacrylate) (PMMA), which served as a gelator to enhance the stability of the electrolytes and dye-sensitized solar cells (DSSCs). Furthermore, bis(trifluoromethane)sulfonimide lithium salt (LiTFSI) and camphorsulfonic acid (C10H16O4S) were separately added to the gel-based electrolytes. The results indicate that adding LiTFSI and C10H16O4S to the gel-based electrolytes effectively enhanced the device efficiency. In particular, the device with the 1:1 + 0.1 M LiTFSI gel-based electrolyte exhibited the optimal efficiency (7.33%), which was higher than that observed in the device with the liquid-based electrolyte. The results also proved that the DSSC devices with the gel-based electrolytes exhibited a longer stability. Therefore, using optimized gel-based electrolytes can enhance the power conversion efficiency and stability of DSSC devices.

Keywords: dye sensitized; based electrolytes; sensitized solar; gel based; efficiency

Journal Title: Materials Research Bulletin
Year Published: 2018

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