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Coexistence of negative and positive electrocaloric effect in Sr and Nb co-doped Pb(Zr,Ti)O3 ferroelectric ceramics

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Abstract The electrocaloric effect has been investigated in Sr and Nb co-doped Pb(Zr,Ti)O 3 (PSNZT) ceramics synthesized by conventional solid state reaction. The coexistence of negative and positive electrocaloric effect… Click to show full abstract

Abstract The electrocaloric effect has been investigated in Sr and Nb co-doped Pb(Zr,Ti)O 3 (PSNZT) ceramics synthesized by conventional solid state reaction. The coexistence of negative and positive electrocaloric effect was revealed in PSNZT ceramics. The electrocaloric response values of −0.38 K at 80 °C and 0.65 K at 180 °C were observed under an electric field of 1.5 kV/mm. The corresponding electrocaloric coefficient values were calculated to be −0.25 K mm kV −1 and 0.43 K mm kV −1 respectively. The mechanism of the coexistence of negative and positive electrocaloric effect was discussed.

Keywords: electrocaloric effect; positive electrocaloric; effect; negative positive; coexistence negative

Journal Title: Materials Letters
Year Published: 2017

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