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Surface modification of alumina membranes via a sol-gel process for antifouling properties

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Abstract Alumina membranes were modified using a SiO 2 sol-gel process to mitigate membrane fouling. The formation of a SiO 2 coating layer resulted in slightly narrowed pore sizes and… Click to show full abstract

Abstract Alumina membranes were modified using a SiO 2 sol-gel process to mitigate membrane fouling. The formation of a SiO 2 coating layer resulted in slightly narrowed pore sizes and reduced pure water permeability. Due to low isoelectric points, SiO 2 -coated membranes have a strong negative surface charge (−130 mV at pH 6.5), which results in the presence of electrostatic repulsion forces against humic acid. The membranes with higher TEOS (tetraethyl orthosilicate) concentrations exhibited higher flux levels during membrane fouling procedures, while the pristine alumina membrane displayed the lowest flux. Thus, inorganic surface modification with amorphous SiO 2 clearly enhances the antifouling properties of pristine alumina membranes.

Keywords: antifouling properties; alumina membranes; gel process; sol gel; surface modification

Journal Title: Materials Letters
Year Published: 2017

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