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Facile fabrication of phenothiazine-tetracyanoquinodimethane co-crystal microwires with ambipolar charge transport characteristics

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Abstract Novel co-crystal microwires based on phenothiazine (PTZ) and tetracyanoquinodimethane (TCNQ) have been fabricated using a facile solution method and fully characterized. The microwires had well-defined shapes, smooth surfaces and… Click to show full abstract

Abstract Novel co-crystal microwires based on phenothiazine (PTZ) and tetracyanoquinodimethane (TCNQ) have been fabricated using a facile solution method and fully characterized. The microwires had well-defined shapes, smooth surfaces and high crystalline. Moreover, the co-crystal microwires exhibited a significant absorption at wavelengths between 900 and 2400 nm owing to the charge-transfer interaction between PTZ and TCNQ. The prototype field-effect transistor with the bottom-gate was directly constructed, exhibiting typical ambipolar charge transport characteristics.

Keywords: transport characteristics; charge transport; ambipolar charge; charge; crystal microwires

Journal Title: Materials Letters
Year Published: 2018

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